SECTION 2 - HAZARDOUS INGREDIENTS |
HAZARDOUS COMPONENTS |
% (by weight) |
CAS # |
EINECS # |
Hazard Symbol |
RISK PHRASES Full Text Section 16 |
1 - 5 C6834-92-0 229-912-9 R-34, 37Sodium metasilicate The remaining components of this product are non-hazardous or are in small enough quantities as to not meet regulatory thresholds for disclosure. These components contain no substances or impurities which would influence the classification of this product. |
SECTION 3 - HAZARDS IDENTIFICATION |
EMERGENCY OVERVIEW Alkaline liquid, prolonged contact may cause skin & eye irritation. Ingestion may cause gastric distress. Hazard Symbols for this product - Xi, Risk Phrases - R36/38 |
POTENTIAL HEALTH EFFECTS |
INHALATION: Breathing concentrated vapors may cause irritation of respiratory tract. |
SKIN: Prolonged contact may cause irritation. |
EYES: Contact with eyes will cause irritation. |
INGESTION: May cause gastric distress, vomiting and diarrhea. |
CARCINOGENICITY No No NoIARC MONOGRAPHS? OSHA REGULATED?NTP? |
SECTION 4 - FIRST AID MEASURES |
INHALATION: Remove affected person to fresh air; wash mouth and nasal passages with water repeatedly; if breathing difficulties persist seek medical attention. |
SKIN: Wash contacted area with soap and water; DO NOT attempt to neutralize with chemical agents; if irritation persists, seek medical attention. |
EYES: Check for and remove contact lenses. Immediately flush eyes for 15 minutes in clear running water while holding eyelids open; seek medical attention immediately. |
INGESTION: Drink large quantities of water or milk; DO NOT induce vomiting; never give anything by mouth to an unconscious person; seek medical attention immediately. |
SECTION 5 - FIRE FIGHTING MEASURES |
GENERAL HAZARDS: Product is alkaline. Products of combustion include compounds of carbon, hydrogen and oxygen, including carbon monoxide. |
EXTINGUISHING MEDIA Carbon dioxide, water, water fog, dry chemical, chemical foam. |
FIRE FIGHTING PROCEDURES Keep containers cool with water spray to prevent container rupture due to steam buildup; floor will become slippery if material is released. Material is alkaline and will irritate the eyes if product is allowed to directly contact the eyes. |
None UNUSUAL FIRE AND EXPLOSION HAZARDS |
HAZARDOUS COMBUSTION PRODUCTS Smoke, fumes or vapors, oxides of carbon. |
SECTION 6 - ACCIDENTAL RELEASE MEASURES |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Material is alkaline and will irritate the eyes if product is allowed to directly contact the eyes. Wash small spills to sanitary sewer. Large spills - confine spill, soak up with approved absorbent, shovel product into approved container for disposal. |
SECTION 7 - HANDLING AND STORAGE |
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect containers from abuse; protect from extreme temperatures. Keep this and other chemicals out of reach of children. |
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION |
HAZARDOUS COMPONENTS |
NIOSH |
ACGIH |
TWA ppm |
TWA mg/m3 |
STEL ppm |
STEL mg/m3 |
TWA ppm |
TWA mg/m3 |
STEL ppm |
STEL mg/m3 |
6 6Sodium metasilicate |
PERSONAL PROTECTION: |
RESPIRATORY PROTECTION: None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134, ANSI Z88.2, or European Standard EN 149 for complete regulations. |
PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs. |
EYE PROTECTION: Chemical splash goggles. Refer to 29 CFR 1910.133, ANSI 87.1, or European Standard EN166. |
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls, apron, or other equipment should be worn to minimize skin contact, safety eyewash station nearby. |
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general. |
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
Pink liquid, mild characteristic odor APPEARANCE AND ODOR |
VAPOR PRESSURE 17 mm Hg @ 20° C |
pH 12.0 |
SPECIFIC GRAVITY (WATER = 1) 1.040 |
212° F ( 100° C ) TCC BOILING POINT / BOILING RANGE |
Complete SOLUBILITY IN WATER |
Non-flammable FLASH POINT |
VISCOSITY Like that of water |
LEL: Not applicable UEL: Not applicable FLAMMABLE LIMITS |
> 1 VAPOR DENSITY (AIR = 1) |
AUTOIGNITION TEMPERATURE Not determined |
EVAPORATION RATE (WATER = 1) < 1 |
SECTION 10 - STABILITY AND REACTIVITY |
X STABILITY UNSTABLE: STABLE: |
CONDITIONS TO AVOID: Extreme temperatures. |
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids. |
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fumes or vapors, and smoke may be produced. |
XWILL NOT OCCUR: HAZARDOUS POLYMERIZATION MAY OCCUR: |
CONDITIONS TO AVOID: None |
SECTION 11 - TOXICOLOGICAL INFORMATION |
Hazardous Components |
EINECS # CAS # |
LD50 of Ingredient (Specify Species and Route) |
(Specify Species) LC50 of Ingredient |
Sodium metasilicate |
6834-92-0 229-912-9 |
1153 mg / kg Oral - rat |
Not established |
SECTION 12 - ECOLOGICAL INFORMATION |
No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be evaluated and approved for each specific biological system. None of the ingredients in this mixture are classified as a Marine Pollutant. |
SECTION 13 - DISPOSAL CONSIDERATIONS |
WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. Refer to 40 CFR 260 - 299 for complete waste disposal regulations for alkaline materials. Consult your local, state, or federal agency before disposing of any chemicals. According to the European Waste Catalogue, waste codes are application specific and should be assigned by the user based on the application for which the product is used. |