60 - 80 F, Xn 3 - 7 Xn 10 - 30 Xi 265-191-7 1309-37-1 215-168-2 64742-89-8 265-192-2 64742-88-7 R-11, 65, 66, 67 R-65, 66, 67 R-36/37/38 Petroleum distillate, aliphatic Petroleum distillate, aliphatic Iron oxide, red (a) The remaining components of this product are non-hazardous or are in small enough quantities as to not meet regulatory thresholds for disclosure. These components contain no substances or impurities which would influence the classification of this product.
(a) The exposure limits of this product, when allowed to enter the environment as dust particulate, are covered under the rules of 29 CFR 1910.1000, Table Z - 3, "All inert or nuisance dusts, whether mineral, inorganic or organic."
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW White paste, flammable, potentially hazardous vapors. Can cause serious or fatal complications if swallowed. Can cause eye and skin irritation upon contact. Inhalation of vapors can cause anesthetic effect leading to death in poorly ventilated areas. Hazard Symbols for this product - F, Xi, Xn. Risk Phrases - R11, 20/22, 36/38
POTENTIAL HEALTH EFFECTS
INHALATION: High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting and malaise.
SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis.
EYES: High vapor concentration or contact may cause irritation and discomfort.
INGESTION: May result in vomiting; aspiration of vomitus into the lungs must be avoided; DO NOT induce vomiting. Minute amounts aspirated into the lungs can produce severe lung injury, chemical pneumonitis, pulmonary edema or death.
CARCINOGENICITY No No NoIARC MONOGRAPHS? OSHA REGULATED?NTP?
SECTION 4 - FIRST AID MEASURES
INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR and seek emergency medical attention.
SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation persists, seek medical attention.
EYES: Check for and remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek medical attention.
INGESTION: DO NOT induce vomiting; if vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs; seek immediate medical attention. Vomiting may be induced only under the supervision of a physician.
SECTION 5 - FIRE FIGHTING MEASURES
GENERAL HAZARDS: Product is flammable. Products of combustion include compounds of carbon, hydrogen and oxygen, including carbon monoxide. Vapors may cause a flash fire or ignite explosively. Vapors may travel a considerable distance to a source of ignition and flash back.
EXTINGUISHING MEDIA Carbon dioxide, water fog, dry chemical, chemical foam.
FIRE FIGHTING PROCEDURES Firefighters must wear full facepiece self - contained breathing apparatus in positive pressure mode. Do not use solid stream of water since stream will scatter and spread fire. Fine water spray can be used to keep fire - exposed containers cool.
Closed containers can explode due to buildup of pressure when exposed to extreme heat. Do not use direct stream of water on pool fires as product may reignite on water surface. Caution - Material is flammable! UNUSUAL FIRE AND EXPLOSION HAZARDS
HAZARDOUS COMBUSTION PRODUCTS Smoke, fumes or vapors, oxides of carbon.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: CAUTION - FLAMMABLE - Evacuate and ventilate area; remove all sources of sparks, ignition and open flames; confine and absorb into approved absorbent; place material into approved containers for disposal; do not wash to sewer or waterway.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect containers from abuse; protect from extreme temperatures. CAUTION - FLAMMABLE - keep away from all sources of ignition. "Empty" containers may contain residue which may form explosive vapors. Do not weld or cut near empty container that has not been professionally reconditioned. Use non-sparking tools when opening and closing containers. Maintain well ventilated work areas to minimize exposure when handling this material.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
RESPIRATORY PROTECTION: None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134, ANSI Z88.2, or European Standard EN 149 for complete regulations.
PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs.
EYE PROTECTION: Chemical splash goggles. Refer to 29 CFR 1910.133, ANSI 87.1, or European Standard EN166.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station nearby.
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
White paste, mild characteristic hydrocarbon odor APPEARANCE AND ODOR
VAPOR PRESSURE 2.0 mm Hg @ 20° C
pH 6.0 - 8.0
SPECIFIC GRAVITY (WATER = 1) 1.640
260° F ( 126.7° C ) TCC BOILING POINT / BOILING RANGE
Miscible SOLUBILITY IN WATER
65° F ( 18.3° C ) TCC FLASH POINT
VISCOSITY Paste
LEL: 0.9% UEL: 6.0% FLAMMABLE LIMITS
> 1 VAPOR DENSITY (AIR = 1)
AUTOIGNITION TEMPERATURE Not determined
EVAPORATION RATE (WATER = 1) < 1
SECTION 10 - STABILITY AND REACTIVITY
X STABILITY UNSTABLE: STABLE:
CONDITIONS TO AVOID: Extreme temperatures, open flames, sparks.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fumes or vapors, and smoke may be produced.
XWILL NOT OCCUR: HAZARDOUS POLYMERIZATION MAY OCCUR:
CONDITIONS TO AVOID: None
SECTION 11 - TOXICOLOGICAL INFORMATION
Hazardous Components
EINECS # CAS #
LD50 of Ingredient (Specify Species and Route)
(Specify Species) LC50 of Ingredient
Petroleum distillate, aliphatic
64742-89-8 265-192-2
Not determined
Not determined
Petroleum distillate, aliphatic
265-191-7 64742-88-7
4700 mg / kg Oral - rat
4100 ppm / 4H Inhalation - rat
Iron oxide, red (a)
1309-37-1 215-168-2
Not established
Not established
SECTION 12 - ECOLOGICAL INFORMATION
No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be evaluated and approved for each specific biological system. None of the ingredients in this mixture are classified as a Marine Pollutant.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. This product may produce hazardous vapors in a closed disposal container creating a dangerous environment. Refer to 40 CFR 260 - 299 for complete waste disposal regulations. Consult your local, state, or federal agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway. According to the European Waste Catalogue, waste codes are application specific and should be assigned by the user based on the application for which the
