10 - 30 Xn 1 - 5 Xn 203-905-0 64742-06-9 265-105-8 111-76-2 R-65, 66, 67 R-20/21/22,36/38 Petroleum distillate, aliphatic Ethylene glycol monobutyl ether (a,b) (a) See Section 15 The remaining components of this product are non-hazardous or are in small enough quantities as to not meet regulatory thresholds for disclosure. These components contain no substances or impurities which would influence the classification of this product.
(b) Indicates an employee's skin exposure shall be prevented or reduced to the extent necessary in the circumstances through the use of gloves, coveralls, goggles, or other appropriate equipment.
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW Red combustible liquid, potentially hazardous vapors. Can cause serious or fatal complications if swallowed. Can cause eye and skin irritation upon contact. Inhalation of vapors can cause anesthetic effect leading to death in poorly ventilated areas. Hazard Symbols for this product - Xn Risk Phrases - R 65, 66, 67
POTENTIAL HEALTH EFFECTS
INHALATION: High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting and malaise.
SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis.
EYES: High vapor concentration or contact may cause irritation and discomfort.
INGESTION: May result in vomiting; aspiration of vomitus into the lungs must be avoided; DO NOT induce vomiting. Minute amounts aspirated into the lungs can produce severe lung injury, chemical pneumonitis, pulmonary edema or death.
CARCINOGENICITY No No NoIARC MONOGRAPHS? OSHA REGULATED?NTP?
SECTION 4 - FIRST AID MEASURES
INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR and seek emergency medical attention.
SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation persists, seek medical attention.
EYES: Check for and remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek medical attention.
INGESTION: DO NOT induce vomiting; if vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs; seek immediate medical attention. Vomiting may be induced only under the supervision of a physician.
SECTION 5 - FIRE FIGHTING MEASURES
GENERAL HAZARDS: Product will support combustion. Products of combustion include compounds of carbon, hydrogen and oxygen, including carbon monoxide.
EXTINGUISHING MEDIA Carbon dioxide, water fog, dry chemical, chemical foam.
FIRE FIGHTING PROCEDURES Self - contained respiratory equipment; cool containers to prevent pressure buildup and possible explosion when exposed to extreme heat. Caution - material will support combustion!
Closed containers can explode due to buildup of pressure when exposed to extreme heat. UNUSUAL FIRE AND EXPLOSION HAZARDS
HAZARDOUS COMBUSTION PRODUCTS Smoke, fumes or vapors, oxides of carbon.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WILL SUPPORT COMBUSTION. Evacuate and ventilate area; confine and absorb into absorbent; place material into approved containers for disposal; refer to SARA Title III, Section 313 40 CFR 372 for details concerning reporting requirements. Do not discharge into lakes, ponds, streams or public waters.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect containers from abuse; protect from extreme temperatures, open flames. This material will support combustion. Keep this and other chemicals out of reach of children.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
RESPIRATORY PROTECTION: None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134, ANSI Z88.2, or European Standard EN 149 for complete regulations.
PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs.
EYE PROTECTION: Chemical splash goggles. Refer to 29 CFR 1910.133, ANSI 87.1, or European Standard EN166.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station nearby.
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Yellow liquid, characteristic odor APPEARANCE AND ODOR
VAPOR PRESSURE 17 mm Hg @ 20° C
pH 6.0 - 8.0
SPECIFIC GRAVITY (WATER = 1) 0.960
212° F ( 100° C ) TCC BOILING POINT / BOILING RANGE
Miscible SOLUBILITY IN WATER
> 200° F (> 93.3° C) FLASH POINT
VISCOSITY Like that of water
LEL: Not applicable UEL: Not applicable FLAMMABLE LIMITS
> 1 VAPOR DENSITY (AIR = 1)
AUTOIGNITION TEMPERATURE Not determined
EVAPORATION RATE (WATER = 1) < 1
SECTION 10 - STABILITY AND REACTIVITY
X STABILITY UNSTABLE: STABLE:
CONDITIONS TO AVOID: Extreme temperatures, open flames.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fumes or vapors, and smoke may be produced.
XWILL NOT OCCUR: HAZARDOUS POLYMERIZATION MAY OCCUR:
CONDITIONS TO AVOID: None
SECTION 11 - TOXICOLOGICAL INFORMATION
Hazardous Components
EINECS # CAS #
LD50 of Ingredient (Specify Species and Route)
(Specify Species) LC50 of Ingredient
Petroleum distillate, aliphatic
64742-06-9 265-105-8
Not established
Not established
Ethylene glycol monobutyl ether (a,b)
203-905-0 111-76-2
470 mg / kg Oral - rat
450 ppm / 4H Inhalation - rat
(a) See Section 15
SECTION 12 - ECOLOGICAL INFORMATION
No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be evaluated and approved for each specific biological system. None of the ingredients in this mixture are classified as a Marine Pollutant.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. This product may produce hazardous vapors in a closed disposal container creating a dangerous environment. Refer to 40 CFR 260 - 299 for complete waste disposal regulations. Consult your local, state, or federal agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway.